基本情况

姓名：叶保辉

性别：男

出生年月：1964-11

籍贯：海南文昌

职位：现任无机化学研究所教授，博士生导师

 

联系方式

电话： +86-020-84112469

传真：暂未填写

邮箱：cesybh@mail.sysu.edu.cn

通讯地址：广东省广州市永利集团3044noc登录入口化学与化学工程学院

邮编：510275

个人网站：暂未填写

 

教育经历

1994年毕业于永利集团3044noc登录入口，获博士学位；
1994年10月至1997年10月在香港科技大学作博士后；
1997年10月到永利集团3044noc登录入口化学与化学工程学院工作，期间获日本学术振兴会（JSPS）资助，在日本九州大学（Kyushu University）作博士后特别研究员（1999,7-2001,6）

 

工作经历

暂无资料

 

讲授课程

曾讲授《无机化学》、《应用无机化学》、《无机化学实验》、《配位化学》等本科生、研究生课程

 

科研方向

研究方向：功能配合物和超分子化学。 主要研究兴趣：(1) 结构新颖的框架、笼状配合物设计和合成及在催化和分离方面的应用；(2) 钌、稀土配合物在传感器和光学材料方面的应用

 

科研项目

1. 仿生水解酶的模研究（广东省自然科学基金，编号021423398）
2. 手性配合物的识别及组装（教育部，编号31240415001）
3. 金属卟啉分子筛类杂化材料的合成及性质研究 （广东省自然科学基金资助，编号031581）
4. 新型金属卟啉多孔聚合物的合成及性质研究 (国家自然科学资助，编号20371052)

 

获奖情况

1. 1996年“混配配合物的生物功能、作用机制及其应用探索”1996年获广东省自然科学一等奖。（第三完成人）
2. 1998年“金属酶体系的结构、机制和模拟研究”获国家教育部科技进步二等奖（基础类）。（第三完成人）
3. 200年“金属酶模型化合物的结构、生物功能、作用机制之间规律性” 获中国高校自然科学二等奖。（第四完成人）

 

论著一览

1. Template Trapping and Crystal Structure of the Magic Number (H2O)21 Cluster in the Tetrahedral Hole of a Nanoscale Global Ion Packed in a Face-Centered Cubic PatternMan-Li Cao, Jin-Ji Wu, Hao-Jun Mo, Bao-Hui Ye*, J. Am. Chem. Soc. 2009, 131, 3458-3459. 
2. Characterization of a Dinuclear MnV=O Complex and Its Efficient Evolution of O2 in the Presence of Water Y. Shimazaki, T. Nagano, H. Takesue, Bao-Hui Ye, F. Tani, Y. Naruta, Angew. Chem. Int. Ed. 2004,43, 98-100. 
3. Metal-organic Molecular Architectures with 2,2’-Bipyridyl-like and Carboxylate LigandsBao-Hui Ye, Ming-Liang Tong, Xiao-Ming Chen*, Coord. Chem. Rev. 2005, 249, 545-565. 
4. Spontaneous Chiral Resolution of mer-[CoII(N,N,O-L3)2] Enantiomers Mediated by p-pInteractionsJin-Ji Wu, Man-Li Cao, Bao-Hui Ye*, Chem. Commun., 2010, 46, 3687-3689. 
5. Interlocking of Molecular Rhombi into a 2D Polyrotaxane Network via p-p Interactions. Crystal Structure of [Cu2(bpa)2(phen)2(H2O)2].2H2O (bpa2- = biphenyl-4,4’-dicarboxylate, phen = 1,10-phenanthroline)Gao-Feng Liu, Bao-Hui Ye, Y.-H. Liu, Xiao-Ming Chen*, Chem. Commun. 2002, 1442-1443. 
6. Novel Dimanganese(II) Complexes with (m-H2O)(m-OAc)2 Bridges. Model for Dimanganese Enzymes Bao-Hui Ye, T. Mak, I. D. Williams and Xiao-Yuan Li*, Chem. Commun. 1997, 1813-1814. 
7. Formation of a Novel Tetranuclear Iron(III) Complex with a m4-PO4 Bridge from 4-Nitrophenyl Phosphate Bao-Hui Ye, Xiao-Yuan Li*, Feng Xue and T. C. W. Mak, Chem. Commun. 1997, 2407-2408. 
8. Ruthenium(II) 2,2′-Bibenzimidazole Complex as a Second-SphereReceptor for Anions Interaction and Colorimeter Ying Cui, Yan-Li Niu, Man-Li Cao, Ke Wang, Hao-Jun Mo, Yong-Rui Zhong, and Bao-Hui Ye*,Inorg. Chem. 2008, 47, 5616-5624 
9. Assembly of a Cubic Nanocage Co8L12 and a Hydrogen-Bonded 3D NbONet Based on the [(HCO3)2]2- Synthon and Water Man-Li Cao, Hong-Guo Hao, Wei-Xiong Zhang, and Bao-Hui Ye*, Inorg. Chem, 2008, 47, 8126-8133 
10. A Copper(II) Ion-Selective ON-OFF Type Fluoroionophore Based on Zinc Porphyrin-Dipyridylamino Yan-Qin Weng, Fan Yue, Yong-Rui Zhong and Bao-Hui Ye*, Inorg. Chem. 2007, 46,7749-7755. 
11. Anion Selective Interaction and Colorimeter by An Optical Metalloreceptor Based on Ruthenium(II) 2,2’-Biimidazole. Hydrogen Bonding and Proton Transfer.Ying Cui, Hao-Jun Mo, Jin-Can Chen, Yan-Li Niu, Yong-Rui Zhong, Kang-Cheng Zheng, and Bao-Hui Ye*, Inorg. Chem, 2007,46, 6427-6436 
12. In Situ Solvothermal Generation of 1,2,4-Triazolates and Related Compounds from Organonitriles and Hydrazine Hydrate: A Mechanism Study Lin Cheng, Wei-Xiong Zhang, Bao-Hui Ye*,Jian-Bin Lin,Xiao-Ming Chen* , Inorg. Chem. 2007, 46, 1135-1143. 
13. Pillared-layer Microporous Metal-organic Frameworks Constructed by Robust Hydrogen Bonds. Synthesis, Characterization, Magnetic and Adsorption Properties of 2,2’-Biimidazole and Carboxylate Complexes.Bing-Bing Ding, Yan-Qin Weng, Zong-Wan Mao, C.-K. Lam, Xiao-Ming Chen, Bao-Hui Ye*, Inorg. Chem. 2005, 44, 8836-8845. 
14. Formation of One-dimensional Metal-water Chain Containing Cyclic Water Hexamers,Bao-Hui Ye*, Bing-Bing Ding, Yan-Qin  Weng, Xiao-Ming Chen, Inorg. Chem. 2004, 43, 6866-6868. 
15. Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between 13C NMR Chemical Shifts and Carboxylate Binding Modes Bao-Hui Ye*, Xiao-Yuan Li, I. D. Williams, Xiao-Ming Chen, Inorg. Chem. 2002, 41, 6426-6431. 
16. The First Two Aqua-bridged Dimagnesium(II) complexes: Structural Models for Active Sites in Dimetallic Hydrolases Bao-Hui Ye, T. Mak, I. D. Willams and Xiao-Yuan Li*, J. Chem. Soc. Dalton Trans. 1998, 1935-1936. 
17. Mononuclear Nickel Complexes Assembled into Two-dimensional Networks via Hydrogen Bonds and p-p Stacking interactions Bao-Hui Ye*, Xiao-Ming Chen, Gen-Qiang Xue and Liang-Nian Ji, J. Chem. Soc. Dalton Trans.1998, 2827-2827. 
18. Mono- and Binuclear Ruthenium(II) Complexes Containing a New Asymmetric Ligand 3-Pyrazyl-as-triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization and DNA-binding PropertiesXiao-Hua Zou, Bao-Hui Ye*, Hong Li, Jing-Gang Liu, Ya Xiong and Liang-Nian Ji, J. Chem. Soc. Dalton Trans. 1999, 1423-1428. 
19. A Novel Method for the Synthesis of Regiospcicically Sulfonated Porphyrin Monomers and Dimmers, Bao-Hui Ye*, Y. Naruta, Tetrahedron 2003, 59, 3593-3601. 
20. Syntheses and Characterization of Aqua-bridged Dimetallic Complexes, M2(m-H2O)(m-OAc)2(Im)4(OAc)2 ( M = Mg2+, Mn2+ and Ni2+). Structural Models for the Active Sites of Dimetallic HydrolasesBao-Hui Ye*, I. D. Williams, X.-Y. Li, J. Inorg. Biochem. 2002, 92, 128-136.

 

相关成果

1994年“黑曲酶发酵生产葡萄糖酸锌” 获中国专利局发明专利，1996年3月27日公开，公开号：CN119213A。