基本情况

姓名:胡鹏

性别:男

出生年月:1983-08

籍贯:湖北省嘉鱼县

职位:教授,博士生导师

 

联系方式

邮箱:hupeng8@mail.sysu.edu.cn

广州市大学城外环东路132号,永利集团3044noc登录入口 

邮编:510006

 

教育经历

2006年‒2011年,中国科学院福建物质结构研究所,有机化学博士(导师:苏伟平研究员)

2002年‒2006年,湖北大学,应用化学学士

 

工作经历

2017年7月-至今               永利集团3044noc登录入口,教授

2016年3月-2017年6月     魏兹曼科学研究所,访问学者,合作导师:Prof. David Milstein

2014年3月-2016年2月     慕尼黑工业大学,博士后,洪堡学者,合作导师:Prof. Thorsten Bach

2012年10月-2013年12月 魏兹曼科学研究所,博士后,合作导师:Prof. David Milstein

2011年7月-2012年9月     中国科学院福建物质结构研究所,助理研究员,合作导师:苏伟平研究员

 

讲授课程

大学化学,波谱解析

 

科研方向

课题组研究方向为:a)基于催化剂设计的化学键断裂和形成的机理研究,及其在新型环境友好的有机反应上的应用;b)光热自由基参与的新型绿色高效化学反应的研究;c)新型高效均相和异相催化剂研究及其在清洁能源方面的应用;d)小分子活化及其在能源物质合成上的应用。

 

(招收硕士研究生、博士研究生、博士后、特聘副研究员、特聘研究员和国内外访问学者。本课题组旨在发展面向未来的化学方法和系统,欢迎对金属有机中间过程、新型催化剂和新型反应设计及应用、清洁能源体系构建及应用等交叉前沿方向感兴趣的学生来课题组进行学习与研究。)

 

科研项目

永利集团3044noc登录入口“百人计划”启动经费

国家自然科学基金青年基金

 

获奖情况

“珠江人才计划”青年拔尖人才

永利集团3044noc登录入口“百人计划”青年杰出人才

福建省自然科学一等奖(排名第三)

Alexander von Humboldt fellowship(德国洪堡奖学金)

PBC fellowship(以色列高等教育委员会PBC奖学金)

中国科学院优秀博士论文

 

论著一览

(41) Qiang Wu, Peng Hu*, Photoinduced C-O Bond Formation through C-C Bond Cleavage of Alcohols by Suppressing Alcohol Oxidation. Adv. Synth. Catal. 2024, 366, 15951605.

 

 

(40) Jia Ruan, Zhongshu Li, Changzhen Yin, Yu-Lin Lu, Zhang-Wen Wei, Peng Hu*, Cheng-Yong Su*, Enantioselective [2+2] Cross-Photocycloaddition Enabled by a Chiral Cage Reactor via Multilevel-Selectivity Control. ACS Catal. 2024, 14, 73217331.

 

 

(39) Jiahui Qian, Yu Zhang, Weining Zhao, Peng Hu*, Decarboxylative halogenation of aliphatic                                                  carboxylic acids catalyzed by iron salts under visible light. Chem. Commun., 2024, 60, 27642767.

 

 

(38) Yu-Lin Lu, Yu-Han Qin, Shao-Ping Zheng, Jia Ruan, Yin-Hui Huang, Xiao-Dong Zhang, Chen-Hui Liu, Peng Hu, Hai-Sen Xu, Cheng-Yong Su* Anion-Mediated Allosteric Catalysis of [2 + 2] Photocycloaddition Based on a Flexible Metallo-Amine Cage for High Diastereoselectivity. ACS Catal. 2024, 14, 94103.

(37) Yahao Huang, Miao Wang, Wei Liu, Qiang Wu, Peng Hu*, Unraveling the Prominent Existence of Trace Metals in Photocatalysis: Exploring Iron Impurity Effects. J. Org. Chem. 2024, 89, 4156−4164. (Highlighted by Org. Process Res. Dev. 2024, 28, 805–815)

 

 

(36) Jinglan Wen, Yahao Huang, Yu Zhang, Hansjörg Grützmacher, Peng Hu*, Cobalt catalyzed practical hydroboration of terminal alkynes with time-dependent stereoselectivity. Nat. Commun. 2024, 15, 2208.

 

 

(35) Miao Wang, Yahao Huang, Peng Hu*, Terminal C(sp3)–H borylation through intermolecular radical sampling. Science 2024, 383, 537544. (https://www.science.org/stoken/author-tokens/ST-1707/full) (Highlighted by National Science Review, 2024, 11, nwae105; 亮点评述:Chin. J. Org. Chem. 2024, 44, 1697-1698; 新华社,光明日报,科学网等媒体报道。)

 

 

(34) Changzhen Yin, Wei Liu, Qiang Wu, Miao Wang, and Peng Hu*, Deconstructive Cyanomethylation Enabled by Radical Cross-Coupling through Multiple C-C Bond and C-H Bond Cleavage. Adv. Synth. Catal. 2023, 365, 10721081. (VIP paper)

 

 

(33) Changzhen Yin, Peng Hu*, Visible-Light-Induced Cross-Dehydrogenative Coupling of Heteroarenes with Aliphatic Alcohols Mediated by Iodobenzene Dichloride. Eur. J. Org. Chem. 2023, e202300015.

 

 

(32) Changzhen Yin, MiaoWang, Zhenxi Cai, Bojun Yuan, Peng Hu*, Visible-Light-Induced Iron Group Metal Catalysis: Recent Developments in Organic Synthesis. Synthesis 2022, 54, 4864–4882. (Invited review)

 

 

(31) Qiang Wu,‡ Wei Liu,‡ Miao Wang, Yahao Huang, Peng Hu*, Iron-catalyzed deconstructive alkylation through chlorine radical induced C–C single bond cleavage under visible light. Chem. Commun., 2022, 58, 9886–9889. (Hot paper)

 

 

(30) Yu Zhang, Jiahui Qian, Miao Wang, Yahao Huang, Peng Hu*, Visible-Light-Induced Decarboxylative Fluorination of Aliphatic Carboxylic Acids Catalyzed by Iron. Org. Lett. 202224, 5972−5976. (Featured by Synfacts, 2022, 18, 1210)

 

 

(29) Zhaofan Jue, Yahao Huang, Jiahui Qian, Peng Hu*, Visible Light-Induced Unactivated δ-C(sp3)- H Amination of Alcohols Catalyzed by Iron. ChemSusChem, 2022, e202201241. (VIP paper, Cover Featured)

 

 

(28) Kang Li‡, Kai Wu‡, Yu-Lin Lu, Jing Guo, Peng Hu, and Cheng-Yong Su*, Creating Dynamic Nanospaces in Solution by Cationic Cages as Multirole Catalytic Platform for Unconventional C(sp)@H Activation Beyond Enzyme Mimics. Angew. Chem. Int. Ed. 2022, 61, e202114070.

(27) Wei Liu,‡ Qiang Wu,‡ Miao Wang, Yahao Huang, Peng Hu*, Iron Catalyzed C-C Single Bond Cleavage of Alcohols, Org. Lett. 202123, 8413–8418. (Featured by Synfacts, 2022, 18, 55; Org. Chem. Highlights, 2022, September 12. Preprint: 10.33774/chemrxiv-2021-85brt-v2)

(26) Miao Wang, Jinglan Wen, Yahao Huang, and Peng Hu*, Selective Degradation of Styrene-Related Plastics Catalyzed by Iron under Visible Light, ChemSusChem, 2021, 5049–5056. (Top Downloaded Article in 2021. Preprint: 10.33774/chemrxiv-2021-mczbs) (专利:ZL 2021 1 0584038.8,一种含芳基聚合物的氧化降解方法及其应用,获广东高校科技成果转化中心最具转化价值知识产权奖。

(25) Miao Wang, Changzhen Yin, Peng Hu*, Ag-catalyzed remote unactivated C(sp3)−H heteroarylation of free alcohols in water, Org. Lett. 202123, 722–726. (Featured by Synfacts2021, 17, 408)

 

(24) Jing-Si Wang, Kai Wu, Changzhen Yin, Kang Li, Yahao Huang, Jia Ruan, Ximin Feng, Peng Hu*, and Cheng-Yong Su*, Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization, Nat. Commun. 2020, 11, 4675.

 

(23) Chuyi Ni#, Yahao Huang#, Tao Zeng, Daohong Chen, Hao Chen, Mingyang Wei, Andrew Johnston, Andrew H. Proppe, Zhijun Ning, Edward H. Sargent, Peng Hu*, and Zhenyu Yang*, Thiophene Cation Intercalation to Improve Band-Edge Integrity in Reduced-Dimensional Perovskites, Angew. Chem. Int. Ed. 2020, 59, 13977–13983.

 

(22) Liang Zhao, Changzhen Yin, Ting Long, Peng Hu, and Zhenyu Yang*, Light-Driven Halide Exchange Facilitates Complete Crystal Transformation in Nanostructured Perovskites. Langmuir, 2020, 36, 3064–3071.

(21) Yinjun Xie, Peng Hu, Yehoshoa Ben-David, and David Milstein*, A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea, Angew. Chem. Int. Ed. 2019, 58, 5105–5109.

(20) Peng Hu and David Milstein*, Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation, Top Organomet. Chem., 2019, 63, 175-192. (Book Chapter of Organometallics for Green Catalysis, Pierre H. Dixneuf and Jean-Francois Soulé (Eds.)

(19) Yinjun Xie,# Peng Hu,# Tatyana Bendikov and David Milstein*, Heterogeneously Catalyzed Selective Hydrogenation of Amides to Alcohols and Amines, Catal. Sci. Technol., 2018, 8, 2784-2788. (#Co-First Author)

(18) Ye Wei,# Peng Hu,# Min Zhang, and Weiping Su*, Metal-Catalyzed Decarboxylative C−H Functionalization, Chem. Rev., 2017, 117, 8864-8907. (#Co-First Author)

(17) Peng Hu, Yehoshoa Ben-David, and David Milstein*, General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2, J. Am. Chem. Soc. 2016138, 6143–6146.

(16) Peng Hu, Yehoshoa Ben-David, and David Milstein*,  Rechargeable Hydrogen Storage System Based on the Dehydrogenative Coupling of Ethylenediamine with Ethanol. Angew. Chem. Int. Ed. 2016, 55, 1061-1064. (Hot paper)

(15) Peng Hu, Thorsten Bach*, Synthesis of Alkyl-Substituted Pyridines by Directed Pd(II)-Catalyzed C–H Activation of Alkanoic Amides. Synlett 2015, 26, 2853–2857.

(14) Peng Hu,# Eran Fogler,# Yael Diskin−Posner, Mark A. Iron, and David Milstein*, A Novel Liquid Organic Hydrogen Carrier System Based on Catalytic Peptide Formation and Hydrogenation. Nat. Commun. 2015, 6, 6859. (#Co-First Author)

(13) Peng Hu, Yael Diskin-Posner, Yehoshoa Ben-David, and David Milstein *, Reusable Homogeneous Catalytic System for Hydrogen Production from Methanol and Water, ACS Catal., 2014, 4, 2649–2652.

(12) Peng Hu, Yaping Shang and Weiping Su*, A General Pd-Catalyzed Decarboxylative Cross-Coupling Reaction between Aryl Carboxylic Acids: Synthesis of Biaryl Compounds, Angew. Chem. Int. Ed. 201251, 5945-5949.

(11) Peng Hu, Min Zhang, Xiaoming Jie and Weiping Su*, Palladium-Catalyzed Decarboxylative C-H Bond Arylation of Thiophenes, Angew. Chem. Int. Ed. 2012, 51, 227 –231.

(10) Peng Hu, Shijun Huang, Jing Xu, Zhangjie Shi*, and Weiping Su*, Construction of Substituted Benzene Rings by Palladium-Catalyzed Direct Cross-Coupling of Olefins: A Rapid Synthetic Route to 1,4-Naphthoquinone and Its Derivatives, Angew. Chem. Int. Ed. 201150, 9926-9930.

(9) Peng Hu, Jian Kan, Weiping Su* and Maochun Hong, Pd(O2CCF3)2/ Benzoquinone: A Versatile Catalyst System for the Decarboxylative Olefination of Arene Carboxylic Acids, Org. Lett. 200911, 2341-2344.

(8) Eran Fogler, Jai Anand Garg, Peng Hu, Gregory Leitus, Linda J. W. Shimon, and David Milstein*, System with Potential Dual Modes of Metal–Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH–Ru Pincer Complexes. Chem. Eur. J., 2014, 20, 15727-15731.

(7) Dipankar Srimani, Ekambaram Balaraman, Peng Hu, Yehoshoa Ben-David and David Milstein*,  Formation of Tertiary Amides and Dihydrogen by Dehydrogenative Coupling of Primary Alcohols With Secondary Amines Catalyzed by Ruthenium Bipyridine-Based Pincer Complexes.  Adv. Synth. Catal., 2013355, 2525–2530.

(6) Yaping Shang, Xiaoming Jie, Huaiqing Zhao, Peng Hu and Weiping Su*, Rh(III)-Catalyzed Amide-Directed Cross-Dehydrogenative Heteroarylation of Pyridines, Org. Lett.201416, 416-419.

(5) Xiaoming Jie, Yaping Shang, Peng Hu, and Weiping Su*,  Palladium-Catalyzed Oxidative Cross-Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading, Angew. Chem. Int. Ed. 201352, 3630-3633.

(4) Yaping Shang, Xiaoming Jie, Jun Zhou, Peng Hu, Shijun Huang, and Weiping Su*, Pd-Catalyzed C–H Olefination of (Hetero)Arenes by Using Saturated Ketones as an Olefin Source, Angew. Chem. Int. Ed201352, 1299 –1303.

(3) Min Zhang, Peng Hu, Jun Zhou, Ge Wu, Shijun Huang and Weiping Su*, Pd-Catalyzed Multidehydrogenative Cross-Coupling between (Hetero)Arenes and Nitroethane to Construct β-Aryl Nitroethylenes, Org. Lett. 201315, 1718-1721.

(2) Ge Wu, Jun Zhou, Min Zhang, Peng Hu and Weiping Su*, Palladium-Catalyzed Direct Arylation of Benzoxazoles with Unactivated Simple Arenes, Chem. Comm. 201248, 8964-8966.

(1) Jun Zhou, Peng Hu, Min Zhang, Shijun Huang, Min Wang and Weiping Su*, A Versatile Catalyst for Intermolecular Direct Arylation of Indoles with Benzoic Acids as Arylating Reagents, Chem.–Eur. J. 201016, 5876–5881.